A mixture is prepared using 27.00 mL of a 0.0758 M weak base (pKa=4.594) , 27.00 mL of a 0.0553 M weak acid (pKa=3.235) and 1.00 mL of 1.25×10−4 M HIn and then diluting to 100.0 mL, where HIn is the protonated indicator. The absorbance measured at 550 nm in a 5.000 cm cell was 0.1102 . The molar absorptivity (????) values for HIn and its deprotonated form In− at 550 nm are 2.26×104 M−1cm−1 and 1.53×104 M−1cm−1 , respectively. What is the pH of the solution?

Answers

Answer 1

Answer:

pH = 4.164

Explanation:

The first process is to find the initial moles for the base (B) & the acid (HA)

i.e.

[tex]= \dfrac{27 mL \times 0.0758 \ moles \ \ of \ B}{1000 \ mL}[/tex]

[tex]=0.0020466[/tex]

[tex]\simeq 2.047\times 10^{-3} \ moles \ of \ B[/tex]

[tex]= \dfrac{27 mL \times 0.0553 \ moles \ \ of \ HA}{1000 \ mL}[/tex]

[tex]=0.0014931[/tex]

[tex]\simeq 1.493\times 10^{-3} \ moles \ of \ HA[/tex]

The acid with base reaction is expressed as;

          HA              +      B         →             A⁻            +         HB⁺

to    1.493 × 10⁻³       2.047 × 10⁻³             -                         -

    -  1.493 × 10⁻³       1.493 × 10⁻³         1.493 × 10⁻³         1.493 × 10⁻³

            0                    5.54 × 10⁻⁴         1.493 × 10⁻³         1.493 × 10⁻³

From observation; both the acid & base weak

Given that:

The pKa for base = 4.594

The pKa for acid = 3.235

Recall that;

pKa = -log Ka

So; Ka = [tex]\mathbf{10^{-Ka}}[/tex]

By applying this:

For Base; Ka = [tex]10^{-4.594}[/tex] = 2.5468 × 10⁻⁵

For Acid:  Ka = [tex]10^{ -3.235}[/tex] = 5.821 × 10⁻⁴

After the reaction; we have the base with its conjugate acid & conjugate base of acid; Thus, since the conjugate acid of the base possesses a higher value of K, it is likely it would be the one to define the pH of the solution.

By analyzing the system, we have:

              HB⁺         + H₂O           ↔           B          +            H₃O⁺

     [tex]\dfrac{1.493\times 10^{-3}}{0.1 \ L}[/tex]                                 [tex]\dfrac{5.54\times 10^{-4}}{0.1 \ L}[/tex]

to   0.01493 M                                 0.00554   M

  -      x                                                   x                                x

    0.01493 - x                                 0.00554 - x                     x

Thus;

[tex]2.5468 \times 10^{-5} = \dfrac{(0.00554 -x)\times x}{(0.01493-x)}[/tex]

Using the common ion effect;

0.00554 - x   [tex]\simeq[/tex]  0.00554   &

0.01493 -  x   [tex]\simeq[/tex]   0.01493

[tex]x = \dfrac{2.5468 \times 10^{-5} \times 0.01493}{0.00554}[/tex]

x =  [H₃O⁺] = 6.8635  × 10⁻⁵

pH = -log(6.8635  × 10⁻⁵)

pH = 4.164


Related Questions

If you were to add glucose to catalase instead of hydrogen peroxide, would bubbles be produced?

Answers

Answer:

No, bubbles would not be produced.

Explanation:

Catalase is an enzyme that catalyses the decomposition of hydrogen peroxide into water (H2O) and oxygen gas (O2). Since oxygen (O2) is a gas, it is physically noticeable as BUBBLES. However, catalase as an enzyme is substrate-specific i.e. it solely acts/breaks down on hydrogen peroxide.

Hence, If one were to add glucose to catalase instead of hydrogen peroxide, oxygen gas observed as BUBBLES will not be produced because catalase will not act on glucose.

What are the coefficients for the reaction _Cl2O5 + _H2O → _HClO3 once it is balanced?

1, 1, 1
1, 1, 2
1, 2, 2
2, 1, 1

Answers

Answer:

1, 1, 2

Explanation:

Answer:

Answer is B. 1, 1, 2

Explanation:

<3

middle school science help please

Answers

Answer:

The answer is 'All of the above'

Explanation:

because the hydrogen ions are represented by the symbol H+, they increase the PH value of a solution if less amount is added but they decrease the PH value of a solution if a larger amount of hydrogen ions are added but still they increase the PH value, and of course, they contribute to a solution by a base.

Answer:

Hydrogen ions are represented by H+.

Explanation:

Hydrogen ions usually decreases the pH value when added to a solution.Hydrogen ions are contributed to a solution by a acid.

In the reaction shown below, which substance is oxidized?
2Na + CuSO4 → Na2SO4 + Cu
A. Na
B. Na2SO4
C. Cu
D. CuSO4

Answers

Answer:

Na

Explanation:

Because sodium loses one electron and becons Na+ and sodium oxidizes

Los of electron is oxidation

Na is oxidised in the given reaction 2Na + CuSO[tex]_4[/tex] → Na[tex]_2[/tex]SO[tex]_4[/tex] + Cu. Therefore, the correct option is option A.

What is oxidation?

When the oxidation state of either a molecule, atom, or ion increases, this is referred to as oxidation. The inverse process is termed reduction, and it happens when electrons are gained when the oxidation status of such an atom, molecule, as well as ion lowers.

When a chemical species oxidizes, its oxidation state rises. Oxidation does not always need the presence of oxygen! The phrase was first used when oxygen induced electron loss inside a process. The present definition is broader.  Na is oxidised in the given reaction 2Na + CuSO[tex]_4[/tex] → Na[tex]_2[/tex]SO[tex]_4[/tex] + Cu.

Therefore,  Na is oxidised in the given reaction 2Na + CuSO[tex]_4[/tex] → Na[tex]_2[/tex]SO[tex]_4[/tex] + Cu. The correct option is option A.

To learn more about oxidation, here:

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explain the early theories of the atomic structure​

Answers

Hi

i hope this helps

Answer:

The Greek atom theory

Explanation:

The concept of the Greek atomos theory is an indivisible particle of matter, goes back to ancient Greece and a man named Democritus held that all matter could be subdivided only until some finite particle was reached.

for each pair of compounds below , identify the one that would be expected to have more ionic character.explain you choice. (a)NaBr or HBr (b)BrCl or FCl​

Answers

Answer:

a)NaBr

b)FCl

Explanation:

To identify which compound is more ionic we will calculate the electronegativity difference.

A) NaBr

Electronegativity of Na = 0.93

Electronegativity of Br = 2.96

Electronegativity difference = 2.96- 0.93 = 2.03

HBr

Electronegativity of H = 2.2

Electronegativity of Br = 2.96

Electronegativity difference = 2.96 - 2.2 = 0.76

NaBr have more ionic character because of large electronegativity difference.

B) BrCl

Electronegativity of Cl = 3.16

Electronegativity of Br = 2.96

Electronegativity difference = 3.16 - 2.96 = 0.2

FCl

Electronegativity of F = 3.98

Electronegativity of Br = 2.96

Electronegativity difference = 3.98 - 2.96 = 1.02

FCl have more ionic character because of large electronegativity difference.

What is the name of Bel on the periodic table

Answers

Answer:

Nobelium or Beryllium

The balanced equation for the syntheis of Iron (I) oxide is below:

If 5.4 moles of Fe react with 4.7 moles of O2, what is the maximum amount of Fe2O3 (in moles) that can be produced? What is the limiting reactant?

a
3.1 moles of Fe2O3 is the maximum amount that can be produced. Oxygen is the limiting reactant.

b
2.7 moles of Fe2O3 is the maximum amount that can be produced. Iron is the limiting reactant.

c
7.1 moles of Fe2O3 is the maximum amount that can be produced. Oxygen is the limiting reactant.

d
10.8 moles of Fe2O3 is the maximum amount that can be produced. Iron is the limiting reactant.

Answers

Answer:

Option B. 2.7 moles of Fe2O3 is the maximum amount that can be produced. Iron is the limiting reactant.

Explanation:

The balanced equation for the reaction is given below:

4Fe + 3O2 —> 2Fe2O3

From the balanced equation above,

4 moles of Fe reacted with 3 moles of O2 to produce 2 moles of Fe2O3.

Next, we shall determine the limiting reactant. This can be obtained as follow:

From the balanced equation above,

4 moles of Fe reacted with 3 moles of O2.

Therefore, 5.4 moles of Fe will react with = (5.4 × 3)/4 = 4.05 moles of O2.

Thus, we can see that only 4.05 moles out of 4.7 moles of O2 given is needed to react completely with 5.4 moles Fe. Therefore, Fe is the limiting reactant and O2 is the excess reactant.

Finally, we shall determine the maximum amount of Fe2O3 produced from the reaction.

In this case, the limiting reactant will be use because it will produce the maximum amount of Fe2O3 as all of it is used up in the reaction.

The limiting reactant is Fe and the maximum amount of Fe2O3 produced can be obtained as follow:

From the balanced equation above,

4 moles of Fe reacted to produce 2 moles of Fe2O3.

Therefore, 5.4 moles of Fe will react to produce = (5.4 × 2)/4 = 2.7 moles of Fe2O3.

Summary:

Limiting reactant => iron (Fe)

Maximum amount of Fe2O3 produce = 2.7 moles

What would have a higher boiling point water or hydrocarbon ( from penny liquid stacking) and why?

Answers

Answer:

High amount of energy is required to dissociate these bonds and hence water molecules have a higher boiling point than expected.

Explanation:

Which of these best describes the relationship between smoke from factories and acid
rain?
A
Smoke travels directly into clouds, creating acid rain.
B
Smoke turns clouds black, which causes them to become more acidic and release
black acid rain.
с
Smoke increases greenhouse gases, which make the water in clouds more acidic
so they release acid rain.
D
Smoke wipes out all the greenhouse gases in the atmosphere, increasing the
acidity of clouds so they create acid rain.

Answers

Answer:

I was about t ask the same question lol

Explanation:

Answer:

For flocabulary read and reaspond weather and erosion the answer is : C , i got the answer cause i got it wrong and i answered b so it is c

Explanation:

C is the correct answer


What is electronegativity?
Explain the periodic trend -
what is it, why is it that way

Answers

Answer:

Electronegativity is a measure of the tendency of an atom to attract a bonding pair of electrons. The Pauling scale is the most commonly used. Fluorine (the most electronegative element) is assigned a value of 4.0, and values range down to caesium and francium which are the least electronegative at 0.7.

Explanation:

Major periodic trends include: electronegativity, ionization energy, electron affinity, atomic radius, melting point, and metallic character. ... These trends exist because of the similar atomic structure of the elements within their respective group families or periods, and because of the periodic nature of the elements

Please help Fast I do not know

Answers

Answer:

So the answer to this question would be C. 400 J

Explanation:

Now for this problem, what is given is a 40 Newtons which would represent the force to be applied to the object, and a distance of 10 meters after the application of the said force. When these two combine, work is done. The unit for work is Joules and this is what we are looking for. The formula to get Joules or for work would be the force applied to the object multiplied by the distance that it travelled after the application of the force. It looks like this

work = force x distance

Joules = Newtons x meter

so let us substitute the variables to their corresponding places

Joules = 40 N x 10 m

Joules = 400 J

IF THIS HELPED YOU PLEASE MARK ME BRAINLIEST! THANKS! :)))))

Scientists use _____ as chemical symbols.

dots
letters
shapes
lines

Answers

Answer:

Letters

Explanation:

Answer:

Letters

Explanation:

Chemical symbols are used to standardize the 'language of chemistry' and to identify elements and atoms in a chemical formula easily. Chemical symbols consist of one or two letters, most often derived from the name of the element.

NEED HELP PLZ ASAP!!!!!

Answers

you need to give more info

Before we can use this equation for
calculations we must first balance it.
What whole number should be placed in the
green box to balance this equation?
2C2H6 + [? ]02 → [ ]CO2 + [ ]H20
Remember, the coefficients should be the
smallest whole numbers possible.

Answers

Answer:

2C₂H₆ +  [7]O₂     →      [4]CO₂ + [6]H₂O

Explanation:

Chemical equation:

C₂H₆ +  O₂     →      CO₂ + H₂O

Balanced chemical equation:

2C₂H₆ +  7O₂     →      4CO₂ + 6H₂O

Step 1:

2C₂H₆ +  O₂     →      CO₂ + H₂O

Left hand side                      Right hand side

C = 4                                     C = 1

H = 12                                    H = 2

O = 2                                     O = 3

Step 2:

2C₂H₆ +  O₂     →      4CO₂ + H₂O

Left hand side                      Right hand side

C = 4                                     C =  4

H = 12                                    H = 2

O = 2                                     O = 9

Step 3:

2C₂H₆ +  O₂     →      4CO₂ + 6H₂O

Left hand side                      Right hand side

C = 4                                     C =  4

H = 12                                    H = 12

O = 2                                     O = 14

Step 4:

2C₂H₆ +  7O₂     →      4CO₂ + 6H₂O

Left hand side                      Right hand side

C = 4                                     C =  4

H = 12                                    H = 12

O = 14                                     O = 14

Potassium Phthalate, KC8H604, is a main source of whistle fuel for many fireworks. A standard firework had 25g of potassium phthalate.​ Calculate the following:
The molar mass of the compound.
How many molecules of fuel there are
The number of moles of Carbon

Answers

Answer:

Explanation:

The given compound is:

           KC₈H₆O₄

Mass of the compound = 25g

Molar mass of the compound

KC₈H₆O₄

   Atomic mass of K  = 39

                             C  = 12

                             H = 1

                             O = 16

Molar mass of the compound  = 39 + 8(12) + 6 (1) + 4(16)

                                                   = 205g/mol

Number of molecules of fuel there in:

Find the number of moles then convert this to number of molecules;

    Number of moles  = [tex]\frac{mass}{molar mass}[/tex]  

    Number of moles  = [tex]\frac{25}{205}[/tex]   = 0.12mol

1 mole of a compound contains 6.02 x 10²³ molecules

 0.12 mole of the phthalate will contain 0.12 x 6.02 x 10²³ =

              7.34 x 10²²molecules

Number of moles of Carbon

  1 mole of the phthalate contains 8 mole of carbon

  0.12 mole of the phthalate will contain 0.12 x  8  = 0.96mole of carbon

How many hydrogen molecules are needed to produce two H2O molecules

Answers

Answer:

There are 2 Hydrogen molecules in H2O

Explanation:

if you look at the symbol for Hydrogen (H) you see that there is a number beside it, to the right. That number shows how many molecules there are of that element.

(Sidenote: If there is no number there is only one molecule)

Hope this helped :)

There are 2per molecules But the question is asking for 2 molecules of it so 2x2= 4... 4 is the answer!

The Lewis diagram for BH2 is:
[H-B-H]-
The electron- pair geometry around the B atom in BH2 is:__________.
There are______lone pair(s) around the central atom, so the geometry of BH2 is________ .

Answers

Answer:

Electron pair geometry- trigonal planar

There is one lone pair around the boron atom

The geometry of BH2 is bent

Explanation:

The valence shell electron pair repulsion theory offers a frame work for determining the shape of molecules based on the number of electron pairs of the valence shell of the central atom in the molecule.

In BH2-, the central atom is boron. There is a lone pair on boron. Owing to the lone pair on boron, the molecular geometry of BH2 is bent.

The geometry of the electron pair around the Boron atom in [tex]BH_2[/tex] is called the trigonal planar. In this case, there is a pair of isolated electrons around Boron, which is the central atom, allowing the [tex]BH2[/tex] molecule to have a folded geometry.

We can arrive at this answer because:

Boron is an element that has three electrons in its valence layer.With this, we can find out that it can make three covalent bonds or donate these electrons to achieve chemical stability.In the case of the [tex]BH_2[/tex] molecule, boron forms covalent bonds with Hydrogen.These bonds allow the Hydrogens to be positioned on either side of the Boron molecule, forcing a pair of their electrons to focus on the center of that molecule, until it is attracted to the extremities.

This allows for a folded geometry around the molecule, allowing Boron to be an exception to the octet rule and achieve stability with 5 electrons in the valence layer.

More information:

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trachea
Meaning of trachea

Answers

Answer:

The trachea, also called the windpipe, is a cartilaginous tube that connects the larynx to the bronchi of the lungs, allowing the passage of air, and so is present in almost all air-breathing animals with lungs. The trachea extends from the larynx and branches into the two primary bronchi. At the top of the trachea the cricoid cartilage attaches it to the larynx. The trachea is formed by a number of horseshoe-shaped rings, joined together vertically by ligaments over their substance and by the trachealis muscle at their ends. The epiglottis closes the opening to the larynx during swallowing.

Explanation:

You asked I answered.

Hope this helped! :)

P.S. If you still don't get where the trachea is, look at the graph below. :)

explain 5 the major innovation made from Abacus to the present fifth generation​

Answers

Answer:

The major innovation made from Abacus to the present fifth generation​ is explained below in details.

Explanation:

Industrial Age - 1600

John Napier, a Scottish noble and diplomat consecrated much of his holiday time to the learning of mathematics. He was particularly engrossed in devising methods to aid estimates. His most famous offering was the discovery of logarithms. He listed logarithmic measures on a set of 10 board rods and thus was capable to do multiplication and division by equaling up numbers on the poles. These became recognized as Napier’s Bones.

what does the phrase sea of electrons describe?? please help

Answers

Answer: Metallic Bonding.In metallic bonds, the valence electrons from the s and p orbitals of the interacting metal atoms delocalize. That is to say, instead of orbiting their respective metal atoms, they form a “sea” of electrons that surrounds the positively charged atomic nuclei of the interacting metal ions.

Explanation:

how dose dissolving sugar in water show that matter is made up of particles

Answers

Answer:

When sugar dissolves, the sugar particles separate from each other and mix with the water particles. When the sugar particles separate, the smaller water particles fit into the spaces between the larger sugar particles. The water and sugar particles are attracted to each other, so they move closer together when they mix.

Explanation:

:  )

Which of the following are examples of QUALITATIVE data? (seiect all that apply)

None these is qualitative data

The sound of a person's voice

The weight of person

The hair color of a person

The body temperature of a person

Answers

Answer:

The hair color of a person

Explanation:

The correct answer would be the hair color of a person.

Qualitative data are data that cannot be measured with any instrument but can only be used to characterize. Unlike quantitative data, these kinds of data can only be observed and recorded but cannot be assigned numerical values, except if coded.

The sound of a person's voice can be quantitative on one hand and qualitative on the other. The intensity of a sound can be measured using a decibel meter and quantitatively assigned a figure, whereas, the quality of the sound can only be characterized and not measured.

Both the weight and the body temperature of a person can be measured using a weighing balance and a thermometer respectively and hence, are considered to be quantitative data when collected.

The color of the hair of a person cannot be measured but can only be observed and characterized. Hence, hair color data constitute qualitative data.

Answer:

hair color

Explanation:

What does a useful scientific explanation include ??

Answers

Answer: scientific explanation

Explanation:

A really good scientific explanation should do two main things: It should explain all the observations and data we have. It should allow us to make testable predictions that we can check using future experiments.

Uncontrolled energy:

causes destruction
produces order
can make things
can do useful work

Answers

Answer:

causes destruction

Help me if you know this pleaseeee

Answers

Answer:

help you with what?

Explanation:

If I change the volume of a solution from 5.00 L to 10.0 L, what was the new
concentration if the original concentration was 4.0 M? Please help me as soon as possible with explanation.

Answers

The new  concentration = 2 M

Further explanation

Dilution is a process of decreasing the concentration of a solution by adding a number of solvents

Can be formulated

M₁V₁=M₂V₂

M₁ = Initial Molarity

V₁ = Initial volume

M₂ = Final Molarity (after dilution)

V₂ = Final volume (after dilution)

V₁=5 L

V₂=10 L

M₁=4 M

The new  concentration(M₂) :

[tex]\tt M_2=\dfrac{V_1.M_1}{V_2}\\\\M_2=\dfrac{5\times 4}{10}\\\\M_2=2~M[/tex]

which group or groups of atoms are the only atoms with f orbitals?

Answers

Answer:

Lanthanides and Actinides

Explanation:

Law of Universal Gravitation (what factors affect gravity and how?)

Answers

Explanation:

Hey there!

According to the law of gravitation, the factors that affects the gravity are:

Mass of the heavenly bodies.Distance from the centre of the body to next body.

Mass of heavenly bodies:The mass of heavenly bodies affect the gravity. We know that gravity is directly proportional to the mass of heavenly bodies. so, when the mass is more there is more gravity and where there is less mass there is less gravity.

Distance from the centre of the body to next body: It is one of the factor to influence gravity. When there is more distance there is less gravity and where there is distance more force is there. Is means gravity is inversely proportional to the distance between the bodies.

Hope it helps...

. A student adds 50 mL of Lead (II) Nitrate solution to 50 mL of potassium iodide. Each
solution is colorless, but when these two liquids are mixed, a yellow precipitate is
observed. What has most likely happened in the experiment?

Answers

Answer:

after the reaction between Lead (II) Nitrate solution and potassium iodide occur Lead(II) iodide  was formed and it's yellow color.

Explanation:

Pb(NO3)2 + KI = KNO3 + PbI2

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