Provided below is the IR and 'H NMR for a compound having the molecular formula of C,H,O, Using this information, determine the degrees of unsaturation for this structure and solve and draw the structure responsible for these spectral data. To validate your answer, you need to assign the type of bond (ie, stretch) responsible for each peak highlighted by a box in the IR. You must also assign each 'H NMR peak (a)-(e) to the correct set of protons in your proposed structure. The integration for each peak has been provided for you. You must label the multiplicity observed for each peak. Is your structure consistent with all of this data? If not, chances are you do not have the correct structure, or the peaks have been assigned incorrectly. In your peer review, offer feedback concerning the accuracy of the submitted structures and spectral assignments. If you believe the answers are incorrect, then you need to provided explanation. In the end, you should all be getting the same correct structure. Please draw the final structure in the box provided underneath the NMR. TH NMR - for clarity, expansions have been provided for peaks that are not a singlets. Proposed Structure: Remember to assign it to the NMR per instructions. IR FREQUENCY TABLE (in wavenumber) Frequency Range (om ) Intensity Group A. Alky! C-H (stretching) Isopropy. -CH(CH), tert-Butyl, -C(CH) ( -5) and 2853-2002 1380-1385 1365-1370 1385-1395 - 1366 (m) and B. Alkenyl C-H(stretching) C- (stretching) R-CH-CH, m) (v) 3010-3095 1620-1600 085-1000 905-920 80-900 (6) (out of plane >C-H bondinga) and BCHCH cafe Esses se s8 s (8) 675-730 960-975 (6) (s) -3300 2100-2260 (8) () cle-RCH-CHR trans-RCH-CHR C. Alkyny! C H (stretching) C-C (stretching) D. Aromatic Ar-H(stretching) Aromatic substitution type (C-Hout-of-plane bendings) Monosubstituted o-Disubstituted m-Disubstituted -3030 and (very s) (very s) (s) 690-710 730-770 735-770 680-725 750-810 800-860 and (very s) (very s) 3590-3650 3200-3550 2500-3000 (sharp ) (broad, s) (broad, p-Disubstituted E. Alcohol, Phenols, and Carboxylic Acids O H (stretching) Alcohols, phenols (dilute solutions) Alcohols, phenols (hydrogen bonded) Carboxylic acids (hydrogen bonded) F. Aldehydes, Ketones, Esters, and Carboxylic Acids C-O (stretching) Aldehydes Ketones Esters Carboxylic acids Amides G. Amines N- H H. Nitriles CON 1630-1780 1690-1740 1680-1750 1735-1750 1710-1780 1630-1690 (s) (s) (s) (s) (s) (5) 3300-3500 (m) 2220-2260 (m) weak edium w - variatie p rowity Abbreviations strong m NMR CHEMICAL SHIFT TABLE (in ppm) CHARACTERISTIC PROTON CHEMICAL SHIFTS Type of Preton Structure Chemical Shin, ppm Cycopropane CHE Primary R-CH Secondary R-CH: Tertiary R; C-11 Vinylic C=C-H Acetylanic triple bond.CC-H Aromate Ar-H Benzyle Arc- Allylic CHCCH Fluorides H-C-F Chlorides H-C-a Bromides H-C-Br Iodides H-C- Alcohol H-C-OH Ethors H-C-OR 33-4 Esters RCOO-C- 3.7-4.1 Esters H-C-COOR 2-22 Acids H-C-COOH 2-26 Carbonyl Compounds H-C-C-0 2-27 Aldehydie R-CH-)C=0 9-10 Hydroxylic R-C-OH 1-55 Phenolie Ar-OH 4-12 Enolic C-C-OH 15-17 Carboxylic ROOOH 10.5-12 Amino RNH, 1-5
Answers
The degree of unsaturation, C-H/2+1. and where C = no. of carbon, H = no. of hydrogen Molecular formula: C7H14O2, 7-14/2+1 = 1. Therefore structure will have one double bond or ring
IR analysis
the band at around 1700 cm-1 is due to the carbonyl group
the band at around 2850 - 2950 cm-1 is due to aliphatic CH stretching
(image) - LINK ATTACHED
1H NMR analysis
the triplet at 4.5 ppm is due to methylene proton attached to an oxygen
the singlet at 2.1 ppm is due to methyl proton attached to the carbonyl group
the quartet at around 1.55 ppm is due to methylene proton attached to another methylene group
the multiplet at 1.5 ppm is due to CH proton attached to two methyl group and one methylene group
the doublet at around 0.9 ppm is due to two methyl proton attached to CH
based on the above analysis the structure of the compound is - image
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Related Questions
An allele is a form of a gene? true or false
Answers
Answer:
true
Explanation:
In the hydrogenation of ethylene using a nickel catalyst, the initial concentration of ethylene is 1.65 mol⋅L−1 and its rate constant (k) is 0.0014 mol⋅L−1⋅s−1 . Determine the rate of reaction if it follows a zero-order reaction mechanism.
Answers
Answer:
.0014 M/s ( (mol*L^-1 / s) )
Explanation:
Since the rate law of a zero order reaction is Rate = k[A]^0, the rate is .0014 * (1.65)^0 = .0014
cosity a letter to our mother
who is in lagos Nigeria telling
her about the
the problem you are
facing
in the school and at
home and suggest solution to
you pproblem
Answers
An answer befitting your question…
Hi mom, I’m having troubles with my teachers. They are cruel to me and I cannot concentrate. I think if we changed schools it would be much better. Thank you mom.
Why do atoms connect to eachother?
Answers
Answer:
To keep from falling apart
Explanation:
Methane and sulfur react to produce carbon disulfide (CS₂), a liquid often used in the production of cellophane.
2CH₄ + S₈ --> 2CS₂ + 4H₂S
Calculate the moles of H₂S produced when 2.25 mol S₈ is used.
Answers
Answer:
9 moles
Explanation:
The balanced chemical equation provided in this question is as follows:
2CH₄ + S₈ → 2CS₂ + 4H₂S
In accordance to the above balanced equation, 1 mole of sulphur (S8) produces 4 moles of hydrogen sulfide (H2S).
Therefore, if 2.25mol of S8 is used, 2.25 × 4 = 9 mol
9 moles of H2S is produced.
g Consider a pure sample of a radioactive isotope with a mass number of (46 A). If the sample has mass of (25.0 B) micrograms and the isotope has a half-life of (4.50 C)x106 years, determine the decay rate for the sample. Give your answer in decays/second and with 3 significant figures.
Answers
This question is incomplete, the complete question is;
g Consider a pure sample of a radioactive isotope with a mass number of (46 + A). If the sample has mass of (25.0 + B) micrograms and the isotope has a half-life of (4.50 + C)x10⁶ years,
determine the decay rate for the sample. Give your answer in decays/second and with 3 significant figures.
A = 1, B = 1, C = 11.
Answer:
the decay rate for the sample is 469,625.898 decay/s
Explanation:
Given the data in the question;
[tex]T_{\frac{1}{2}[/tex] = ( 4.50 + C ) × 10⁶ years
C = 11
[tex]T_{\frac{1}{2}[/tex] = ( 4.50 + 11 ) × 10⁶ years
[tex]T_{\frac{1}{2}[/tex] = 15.50 × 10⁶ years
[tex]T_{\frac{1}{2}[/tex] = 15.50 × 10⁶ × 365 × 24 × 60 × 60
λ = 0.693 / [tex]T_{\frac{1}{2}[/tex]
so
λ = 0.693 / ( 15.50 × 10⁶ × 365 × 24 × 60 × 60 )
also
N = ( 25.0 + B )
B = 1
N = ( 25.0 + 1 )
N = 26 × 10⁻⁶
isotope with a mass number of ( 46.0 + A ) , A=1
= ( 46.0 + 1 ) = 47
N = 26 × 10⁻⁶( 1/47 )( 1 / 1.67 × 10⁻²⁷ ) = 3.31252 × 10²⁰
R = λN
so
R = (0.693 / ( 15.50 × 10⁶ × 365 × 24 × 60 × 60 )) × (3.31252 × 10²⁰)
R = 1.41773 × 10⁻¹⁵ × (3.31252 × 10²⁰)
R = 469,625.898 decay/s
Therefore, the decay rate for the sample is 469,625.898 decay/s
PDF on Unit operation 1 and 2
Answers
> Question 20 3.3 pts A gas occupies 500.0 mL at a temperature of 27.0°C. What is the volume at 15.0°C? (Remember to convert °C to Kelvin.) Use Charles' Law V1T2 = V2T1 © 1500 O 480 0 350 900
Answers
Answer:
480.0 mL
Explanation:
Step 1: Given data
Initial volume (V₁): 500.0 mLInitial temperature (T₁): 27.0 °CFinal volume (V₂): ?Final temperature (T₂): 15.0 °CStep 2: Convert the temperatures to the Kelvin scale
We will use the following expression.
K = °C + 273.15
K = 27.0°C + 273.15 = 300.2 K
K = 15.0°C + 273.15 = 288.2 K
Step 3: Calculate the final volume
Assuming ideal behavior and constant pressure, we can calculate the final volume using Charles' law.
V₁ × T₂ = V₂ × T₁
V₂ = V₁ × T₂ / T₁
V₂ = 500.0 mL × 288.2 K / 300.2 K = 480.0 mL
what type of forces are unequal forces that cause a change in an object's motion such as speed or direction
Answers
Answer:
Unbalanced forces are not equal, and they always cause the motion of an object to change the speed and/or direction that it is moving.
Explanation:
When two unbalanced forces are exerted in opposite directions, their combined force is equal to the difference between the two forces.
The magnitude and direction of the net force affects the resulting motion
This combined force is exerted in the direction of the larger force
For example, if two students push on opposite sides of a box sitting on the floor, the student on the left pushes with less force (small arrow) on the box than the student on the right side of the box (long arrow).
The resulting action (net force: smaller arrow to the right of the = shows that the box will change its motion in the direction of the greater force
If unbalanced forces are exerted in the same direction, the resulting force (net force) will be the sum of the forces in the direction the forces are applied.
When forces act in the same direction, their forces are added. When forces act in opposite directions, their forces are subtracted from each other.
Unbalanced forces also cause a nonmoving object to change its motion
If there is no net force acting on the object, the motion does not change. If there is a net force acting on an object, the speed of the object will change in the direction of the net force.
A percent composition analysis yields
22.6% phosphorus (P) and 77.4%
chlorine (CI). What is the empirical
formula for the compound?
А
B
P2C17
PCI:
Answers
Answer:
PCl₃
Explanation:
To determine the empirical formula of a compound, we need to follow a series of steps.
Step 1: Divide each percent composition by the atomic mass of the element
P: 22.6/30.97 = 0.729
Cl: 77.4/35.45 = 2.18
Step 2: Divide all the numbers by the smallest one, i.e. 0.729
P: 0.729/0.729 = 1
Cl: 2.18/0.729 ≈ 3
The empirical formula of the compound is PCl₃.
How do prevailing winds affect air temperature?
Answers
Answer:
Explanation:
Prevailing winds bring air from one type of climate to another. For example, warm winds that travel over water tend to collect moisture as they travel; the water vapor in the air will condense as it moves into colder climates, which is why temperate coastal areas often receive heavy rainfall
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As mentioned, every step in the Fischer esterification mechanism is an equilibrium. As such, the reaction conditions are chosen in such a way to drive reaction to completion. a. For the reaction you have chosen, calculate the number of moles of carboxylic acid and the number of moles of alcohol given using the starting volumes given in the experiment
Answers
Answer:
Hello your question lacks some required information attached below is the missing information
answer :
number of moles
Acetic acid = 0.061199 mole
Alcohol = 0.027320 mole
Explanation:
The starting volumes : 2.5mL of either alcohol and 3.5mL of either acid
for the purpose of this solution I will take 2.5 mL of 1-butanol and 3.5 mL of acetic acid
mass of 1-Butanol = 2.5 mL * 0.81 g/mol = 2.025 g
∴ number of moles of 1-butanol = 2.025g / 74.12 g/mol = 0.027320 mole
mass of acetic acid = 3.5 mL * 1.05 g/mol = 3.675 g
∴ number of moles of Acetic acid = 3.675 g/ 60.05 g/mol = 0.061199 mole
Reaction equation
CH3-CH2-CH2-CH2-OH + CH3-COOH + H+ (cat) ↔ CH3-CH2-CH2-CH2-O-CO-CH3 + H2O
Question 6 of 10
What could make AG become negative at a given enthalpy and entropy?
A. Changing the temperature
B. Changing the concentrations
C. Changing the pressure
D. Changing the volume
SUBMIT
Answers
Answer:
A via A P E X
The entity that would make ΔG to become negative at a given enthalpy and entropy is Changing the temperature (Option A)
Gibbs free energyΔG = ΔH – TΔS
Where
ΔG is the Gibbs free energy ΔH is the enthalpy changeT is the temperature ΔS is the change in entropyNOTE
ΔG = +ve (non spontaneous)
ΔG = 0 (equilibrium)
ΔG = –ve (spontaneous)
From the Gibbs free energy equation, we can see that the entities that makes us the equation are
Enthalpy, ΔHEntropy, ΔSTemperature, TThus, we can conclude that the correct answer to the question is: changing the temperature (Option A) since the equation has nothing to do with neither concentration, pressure nor volume
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d. If you were to open the carbonated drink bottle after shaking, what would you expect to happen and why? If you were to open the water bottle after shaking, what would you expect to happen and why?
Answers
Shaking causes small bubbles, which helps the soda's carbon dioxide escape faster. The gas will gradually escape from the liquid as bubbles once the can is opened, and the soda will become "flat." The dissolved gas takes a long time to escape if the liquid is treated gently.
C3H8(g) + 5O2(g) ⟶ 3CO2(g) + 4H2O(g) H = -2220 kJ If 865.9 g of H2O is produced during this combustion, how much heat is generated? Do not include the negative sign in your answer. Express the answer to the nearest whole number, or round to the nearest ones place. The molar mass of H2O is 18.02 g/mol.
Answers
Answer:
3 × 10⁴ kJ
Explanation:
Step 1: Write the balanced thermochemical equation
C₃H₈(g) + 5 O₂(g) ⟶ 3 CO₂(g) + 4 H₂O(g) ΔH = -2220 kJ
Step 2: Calculate the moles corresponding to 865.9 g of H₂O
The molar mass of H₂O is 18.02 g/mol.
865.9 g × 1 mol/18.02 g = 48.05 mol
Step 3: Calculate the heat produced when 48.05 moles of H₂O are produced
According to the thermochemical equation, 2220 kJ of heat are evolved when 4 moles of H₂O are produced.
48.05 mol × 2220 kJ/4 mol = 2.667 × 10⁴ kJ ≈ 3 × 10⁴ kJ
What is the precipitation like in the arctic tundra?
Use this website to answer the question: https://thewildclassroom.com/biomes/artictundra-2/
Question 4 options:
In summer, it typically rains less than 5 cm (<2 inches), while in winter it rains 25–44 cm (10–17 inches).
There is an average of 20 – 35 inches of rainfall a year.
The range is from 15-25cm (6-10 inches) a year where most falls as snow.
It can can also be called a cold desert due to its lack of precipitation.
Answers
Answer:
In summer, it typically rains less than 5 cm (<2 inches), while in winter it rains 25–44 cm (10–17 inches).
Explanation:
because tundra vegetation is mostly found in desert areas
how many atoms of carbon are in a diamond with a mass of 0.568 g?
Answers
Answer:
There are 2.85 x 10^22 atoms of carbon in a diamond with a mass of 0.568 g.
Hope this helps! :)
How many grams of Pb are there in a sample of Pb that contains 1.15×1024 atoms? grams
Answers
[tex]\text{mass of Pb = 1.15 × 10²⁴ Pb atoms} × \frac{\text{1 mol Pb}}{\text{6.022 × 10²³ Pb atoms}} × \frac{\text{207.2 g Pb}}{\text{1 mol Pb}}[/tex]
[tex]\boxed{\text{mass of Pb = 396 g}}[/tex]
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- Electrons always fill orbitals in the same order. Each s orbital holds 2 electrons, each set of p orbitals holds 6 electrons, each set of d orbitals holds 10 electrons, and each set of f orbitals holds 14 electrons. The order in which orbitals are filled, from first to last, is:
1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d 7p
Beryllium has 4 electrons. What is the electron configuration of beryllium?
A.
2s^22p^2
B.
1s^22s^2
C.
2s^4
D.
4p^1
Answers
Answer:
[tex]1s^2\, 2s^2[/tex].
Explanation:
Electron orbitals in an atom (e.g., [tex]1s[/tex]) are denoted with:
A number, denoting the shell (principal energy level) of this orbital, andA letter, denoting the shape of this orbital ([tex]s[/tex], [tex]p[/tex], [tex]d[/tex], etc.)
There are two aspects to consider when finding the electron configuration of an atom:
The number of electrons that each type of orbitals could hold, andThe order in which the orbitals are filled.The [tex]s[/tex] orbital in each shell could hold up to [tex]2 \times 1 = 2[/tex] electrons (one [tex]s\![/tex] orbital per shell, with up to two electrons.)
The [tex]p[/tex] orbitals in each shell could hold up to [tex]2 \times 3 = 6[/tex] electrons (three [tex]p\![/tex] orbitals per shell, with up to two electrons in each orbital.)
The [tex]d[/tex] orbitals in each main shell could hold up to [tex]2 \times 5 = 10[/tex] electrons (five [tex]d\![/tex] orbitals per shell, with up to two electrons in each orbital.)
Refer to the order in which the orbitals are filled (Aufbau principle.)
The first orbital to be filled would be [tex]1s[/tex] (the [tex]s[/tex] orbital of the first shell,) accommodating up to [tex]2[/tex] electrons.The second orbital to be filled would be [tex]2s[/tex] (the [tex]s[/tex] orbital of the second shell,) accommodating up to [tex]2[/tex] electrons.All four electrons of Beryllium are thus assigned to the [tex]1s[/tex] and [tex]2s[/tex] orbitals. In a ground-state Beryllium atom, orbitals [tex]2p[/tex] and beyond would contain no electrons.
Notation:
Two electrons in the [tex]1s[/tex] orbital: [tex]1s^{2}[/tex] (the superscript denotes the number of electrons in this orbital (or group of orbitals).)Two electrons in the [tex]2s[/tex] orbital: [tex]2s^2[/tex].Write the non-empty orbitals in the order by which they are filled:
[tex]1s^2\, 2s^2[/tex].
In the oxidation of iron; how many grams of iron (III) oxide will be produced from 6.20 mol of Fe?
4Fe(s) + 3O2(g) --> 2Fe2O3(s)
Answers
Answer:
496 g of Fe₂O₃.
Explanation:
The balanced equation for the reaction is given below:
4Fe + 3O₂ —> 2Fe₂O₃
From the balanced equation above,
4 moles of Fe reacted to produce 2 moles of Fe₂O₃.
Therefore, 6.20 moles of Fe will react to produce = (6.20 × 2)/4 = 3.1 moles of Fe₂O₃
Finally, we shall determine the mass of 3.1 moles of Fe₂O₃. This can be obtained as follow:
Mole of Fe₂O₃ = 3.1 moles
Molar mass of Fe₂O₃ = (56 × 2) + (3×16)
= 112 + 48
= 160 g/mol
Mass of Fe₂O₃ =?
Mass = mole × molar mass
Mass of Fe₂O₃ = 3.1 × 160
Mass of Fe₂O₃ = 496 g
Therefore, 496 g of Fe₂O₃ were produced from the reaction.
What is the molecular geometry of COF2?
Answers
Answer:
trigonal planar
Explanation:
Which organism dna will differ the most from the leopard
Answers
Answer:
Lancelet
Explanation:
This is because a Lancelet is a small elongated marine invertebrate that lacks all of the physiological and biological traits of a leopard
What happens to the amplitude of waves when two waves overlap and are out of phase with each other?
Answers
Answer:
Also called superposition. When overlapping waves produce a wave with an amplitude that is the sum of the individual waves. When overlapping waves produce a wave with an amplitude that is less than the sum of the individual waves.
Explanation:
What class of chemicals is responsible for ozone depletion?
Answers
How many moles of carbon dioxide are produced when 0.25 mole of butane is consumed?
Answers
Answer:
1
Explanation:
Let's write the equation first:
[tex]C_{4}H_{10} + \frac{13}{2} O_{2} -> 4 CO_2 +5 H_{2}O[/tex]
So 1 mole of butane reacts to give 4moles of Carbon diOxide.
thus , 0.25 mole of butane will react to give = 4 * 0.25= 1 mole Carbon diOxide
True or false solar power take power from wind and uses it to make electricity
Answers
An electromagnet is the most powerful type of magnet there is. It is a magnet with a current running through it that can be turned on and off. Why might it be useful to be able to turn the electromagnet on and off?(1 point) 1
to not waste electricity
to control the strength of the magnet
to reduce wearing out of the magnet over time
to latch onto and let go of objects
What does electric current measure?(1 point) 2
how quickly electrical energy moves in a circuit
how frequently electrical energy moves in a circuit
how much electrical energy moves in a circuit
how well electrical energy moves in a circuit
How is a magnetic field produced?(1 point) 3
when an object has an electric charge
when electrons move through a circuit
when a current runs through a conductor
when an electromagnetic field interacts with a magnet
Which statement best describes how an electromagnetic motor works?(1 point) 4
Electrons are moved through a magnet, creating a circuit. That circuit interacts with a current, moving the conductor in the orientation of the field.
Electrons are moved through a circuit, creating a current. That current interacts with a magnet, moving the conductor in the orientation of the field.
Electrons are moved through a current, creating a circuit. That circuit interacts with a magnet, moving the conductor in the orientation of the field.
Electrons are moved through a magnet, creating a current. That current interacts with a circuit, moving the conductor in the orientation of the field.
Electromagnetism in Use Quick Check
5 of 5Items
Item 5
Use the image to answer the question.
A diagram shows a wire carrying a current in vertical direction. The magnetic field drawn using compass needles around the wire are concentric circles in a plane perpendicular to the direction of current.
What are the particles demonstrating in this image?
(1 point) 5
electric field
electromagnetic field
electromagnetic motor
magnetic field
Answers
Answer:
1. to latch onto and let go of eggs
2. how quickly electrical energy moves in a circuit
3. when a current runs through a conductor
4. Electrons are moved through a circuit, creating a current. That current interacts with a magnet, moving the conductor in the orientation of the field.
5. electromagnetic field
How to find the net ionic of an equation
Answers
For example:
Balanced Chemical equation:
HClO₂(aq) + NaOH(aq) → H₂O(l) + NaClO₂ (aq)
Ionic equation:
H⁺(aq) + ClO₂⁻(aq) + Na⁺(aq) + OH⁻(aq) → H₂O(l) + Na⁺(aq) + ClO₂⁻ (aq)
Net ionic equation:
H⁺(aq) + OH⁻(aq) → H₂O(l)
The ClO₂⁻(aq) and Na⁺ (aq) are spectator ions that's why these are not written in net ionic equation. The water can not be splitted into ions because it is present in liquid form.
Spectator ions:
These ions are same in both side of chemical reaction. These ions are cancel out. Their presence can not effect the equilibrium of reaction that's why these ions are omitted in net ionic equation.
2 C8H18 + 25 O2 → 16 CO2 + 18 H2O
How many moles of CO2 can form from 17.5 moles of octane?
Answers
Answer:
140 mol CO₂.
Explanation:
2 C₈H₁₈ + 25 O2 → 16 CO₂ + 18 H₂OIn order to convert from moles of octane (C₈H₁₈) into moles of CO₂, we can use a conversion factor with the stoichiometric coefficients of the balanced reaction:
17.5 mol C₈H₁₈ * [tex]\frac{16molCO_2}{2molC_8H_{18}}[/tex] = 140 mol CO₂140 moles of CO₂ can be produced from 17.5 moles of octane.
Which object will have more potential energy (PE), a book on the edge of a small bookshelf or a penny sitting on the edge of the Empire State building? EXPLAIN your reasoning.
Answers
Answer: I dont know
Explanation: figure it out