Which of the following is NOT a reason for the experimental volume of the flask to be incorrect?

The constant temperature water bath decreases the volume occupied by the gas.

The volume labeled on the flask is not an accurate measure of the total volume of the flask.

The HCl solution added to the flask decreases the volume occupied by gas.

The rubber stopper used to seal the flask decreases the volume occupied by the gas.

Answers

Answer 1

Answer:

2

Explanation:

i dont andesdant

Answer 2

The experimental volume of the flask is found  to be incorrect as the  volume labeled on the flask is not an accurate measure of the total volume of the flask as it will result in errors.

What are errors?

Errors in chemical analysis result when there is a difference between observed value and the true value.If the magnitude of errors is large , it results in decrease in accuracy, reproducibility, and precision.

There are three types of errors:1) random error 2) systematic error 3) human error.The cause of random errors are difficult to quantify while the human errors can be minimized by taking a range of readings to reduce the error.

Errors while measuring boiling point may be human errors while noting down the boiling temperature or instrumental or systematic error if there is a fault in the thermometer.

Learn more about errors,here:

https://brainly.com/question/15810279

#SPJ2


Related Questions

Which element can form acidic compounds? Check all that apply.
Sulfur
rubidium
arsenic
selenium
silicon
zenon
antimony

Answers

The elements that can form acidic compounds are sulfur, arsenic, selenium, and antimony.

Sulfur (S), arsenic (As), selenium (Se), and antimony (Sb) are the elements that can form acidic compounds. These elements have the ability to gain electrons or donate hydrogen ions, resulting in the formation of acidic species.

Sulfur is commonly found in various acidic compounds, such as sulfuric acid (H_{2}SO_{4}), sulfurous acid ([tex]H_{2}SO_{3}[/tex]), and sulfides (e.g., hydrogen sulfide, H2S). Arsenic can form acids like arsenic acid ([tex]H_{3}AsO_{4}[/tex]) and arsenous acid (H_{3}AsO_{}). Selenium can form selenous acid ([tex]H_{2}SeO_{3}[/tex]) and selenic acid (H_{2}SeO_{4}). Antimony can react with oxygen to form antimony pentoxide ([tex]Sb_{2}O_{5}[/tex]), which can further react with water to produce antimony acid (HSb([tex]OH_{6}[/tex])).

On the other hand, rubidium (Rb), silicon (Si), and xenon (Xe) do not typically form acidic compounds. Rubidium is an alkali metal and is more likely to form basic compounds. Silicon is a nonmetal and is commonly found in covalent compounds rather than acidic ones. Xenon is a noble gas and is generally inert, meaning it does not readily form compounds, including acidic ones.

In summary, sulfur, arsenic, selenium, and antimony are the elements that can form acidic compounds, while rubidium, silicon, and xenon do not typically exhibit acidic properties.

Learn more about compounds here: https://brainly.com/question/13762398

#SPJ11

The mole fraction of O2 in air is 0.21. If the total pressure is 0.83 atm and kH is 1.3 x 10-3 M/atm for oxygen in water, calculate the solubility of O2 in water.
2.3 x 10⁻⁴ M
1.1 x 10⁻³ M
2.7 x 10⁻⁴ M
1.3 x 10⁻³ M
Impossible to determine

Answers

Given that the mole fraction of O2 in the air is 0.21, the total pressure is 0.83 atm, and Henry's law constant (kH) for O2 in water is 1.3 x 10-3 M/atm, the solubility of O2 in water can be calculated to be 2.7 x 10⁻⁴ M.

According to Henry's law, the solubility of a gas (in this case, O2) in a liquid (water) is given by the equation: C = kH * P, Where: C is the concentration of the gas in the liquid (solubility),kH is Henry's law constant for the specific gas, P is the partial pressure of the gas. Given that the mole fraction of O2 in the air is 0.21, we can calculate the partial pressure of O2 in the air as follows: PO2 = XO2 * PT, Where: PO2 is the partial pressure of O2, XO2 is the mole fraction of O2 in air, PT is the total pressure. Substituting the given values, we have PO2 = 0.21 * 0.83 atm = 0.17343 atm. Now, we can calculate the solubility of O2 in water using Henry's law: C = kH * P = (1.3 x 10-3 M/atm) * (0.17343 atm) ≈ 2.7 x 10⁻⁴ M.

To learn more about Henry's law, click here: brainly.com/question/30636760

#SPJ11

At 45.0 C and a pressure of 9.9 kPa a sample of gas has a volume of 1.033 L. If the pressure is increased to 1245 kPa what will the new volume be?

Answers

Answer:

The new volume will be 8.2 x 10⁻³ L or 0.0082 L.

Explanation:

Since our temperature remains constant, apply Boyle's Law:

P₁V₁ = P₂V₂

Plug in the initial pressure and volume on the left side, and the new pressure on the right:

9.9(1.033) = 1245(V₂)

V₂ = (9.9(1.033)) / 1245

V₂ = 8.2 x 10⁻³ L or 0.0082 L

A major component of gasoline is octane. When octane is burned in air, it chemically reacts with oxygen gasto produce carbon dioxideand water.
What mass of carbon dioxide is produced by the reaction ofof octane?
Round your answer tosignificant digits.
Please be detailed with your explanation.

Answers

The mass of carbon dioxide produced by the combustion of octane can be calculated using the balanced chemical equation for the reaction and the molar mass of octane and carbon dioxide.

The balanced chemical equation for the combustion of octane (C8H18) is:

2 C8H18 + 25 O2 → 16 CO2 + 18 H2O

From the balanced equation, we can see that for every 2 moles of octane burned, 16 moles of carbon dioxide are produced. To calculate the mass of carbon dioxide, we need to convert the moles of octane to moles of carbon dioxide using the molar ratio.

The molar mass of octane is approximately 114.22 g/mol, and the molar mass of carbon dioxide is approximately 44.01 g/mol. Therefore, the molar ratio of octane to carbon dioxide is 2:16 or 1:8.

To calculate the mass of carbon dioxide produced, we can use the formula:

Mass of carbon dioxide = (moles of octane) × (molar ratio) × (molar mass of carbon dioxide)

The exact mass calculation would require the quantity of octane, but once the moles of octane are known, the mass of carbon dioxide can be determined using the formula above.

Learn more about molar mass, below:

https://brainly.com/question/31545539

#SPJ11

what is the minimum number of atoms that could be contained in the unit cell of an element with a body-centered cubic lattice? a. 1 atom b. 2 atoms
c. 3 atoms
d. 4 atoms e. 5 atoms

Answers

The minimum number of atoms that could be contained in the unit cell of an element with a body-centered cubic (BCC) lattice is 2 atoms.

In a body-centered cubic lattice, each corner of the cube is occupied by one atom, and there is an additional atom at the center of the cube. This arrangement gives rise to a total of 2 atoms per unit cell.

The corner atoms are shared between adjacent unit cells, contributing 1/8th of an atom to each cell, while the atom at the center is fully contained within the unit cell.

Therefore, the minimum number of atoms in the unit cell of a BCC lattice is 2.

To learn more about unit cell here brainly.com/question/13110055

#SPJ11

which of the following statements are true regarding the remainder of the experiment if the scientist wants to use the combined gas law to calculate different properties?a.the pressure must stay at 200 kpa, but the volume, temperature, and amount can change.b.the volume must stay at 300 ml, but the pressure, temperature, and amount can change.

Answers

If the scientist intends to apply the combined gas law to determine various attributes, the following statement is accurate: (A) The pressure must remain at 200 kPa, but the volume, temperature, and amount can change.

Among the statements provided:

A. The statement "The pressure must stay at 200 kPa, but the volume, temperature, and amount can change" is true regarding the remainder of the experiment if the scientist wants to use the combined gas law to calculate different properties. In the combined gas law, the pressure is a constant value, while the volume, temperature, and amount of gas can vary.

B. The statement "The volume must stay at 300 mL, but the pressure, temperature, and amount can change" is not true regarding the remainder of the experiment if the scientist wants to use the combined gas law. The combined gas law allows for changes in all four variables: pressure, volume, temperature, and amount of gas.

C. The statement "The temperature must stay at 900 K, but the pressure, temperature, and amount can change" is not true regarding the remainder of the experiment if the scientist wants to use the combined gas law. The combined gas law considers variations in temperature along with other variables.

D. The statement "The amount must stay at 0.008 mol CO₂, but the temperature, pressure, and volume can change" is not true regarding the remainder of the experiment if the scientist wants to use the combined gas law. The combined gas law takes into account changes in all four variables, including the amount of gas.

In summary, only statement A is true regarding the remainder of the experiment if the scientist wants to use the combined gas law.

To know more about the combined gas law refer here :

https://brainly.com/question/13154969#

#SPJ11

Complete question :

Which of the following statements are true regarding the remainder of the experiment if the scientist wants to use the combined gas law to calculate different properties?

A. The pressure must stay at 200 kPa, but the volume, temperature, and amount can change.

B. The volume must stay at 300 mL, but the pressure, temperature, and amount can change.

C. The temperature must stay at 900 K, but the pressure, temperature, and amount can change.

D. The amount must stay at 0.008 mol CO2, but the temperature, pressure. and volume can change. are filled with comcsodiocodec

SCIENCE ANSWER ASAP PLEASE!!

Answers

A = independent
b = dependent

Ozone (o3) in the atmosphere can be converted to oxygen gas by reaction with nitric oxide (no). Nitrogen dioxide is also produced in the reaction. What is the enthalpy change when 8. 50l of ozone at a pressure of 1. 00 atm and 25°c reacts with 12. 00 l of nitric oxide at the same initial pressure and temperature? [δh°f(no) = 90. 4 kj/mol; δh°f(no2) = 33. 85 kj/mol; δh°f(o3) = 142. 2 kj/mol]

Answers

The enthalpy change when 8.50 L of ozone at a pressure of 1.00 atm and 25°C reacts with 12.00 L of nitric oxide at the same initial pressure and temperature is -277.5 kJ/mol.

The enthalpy change when 8.50 L of ozone at a pressure of 1.00 atm and 25°C reacts with 12.00 L of nitric oxide at the same initial pressure and temperature can be calculated by the given equation. The balanced equation for the reaction is:2O3(g) + 2NO(g) → 2NO2(g) + 3O2(g)The enthalpy change for the given reaction can be determined using Hess’s law. Hess’s law states that the enthalpy change of a reaction is independent of the route taken, provided that the initial and final conditions are the same.

Since the given reaction can be expressed as a sum of a series of known reactions, Hess’s law can be used to calculate the enthalpy change.Using the given data, the enthalpy change for the reaction can be calculated as follows:δH° = 2 × [ΔH°f(NO2(g))] + 3 × [ΔH°f(O2(g))] - 2 × [ΔH°f(O3(g))] - 2 × [ΔH°f(NO(g))]δH° = 2 × [33.85 kJ/mol] + 3 × [0 kJ/mol] - 2 × [142.2 kJ/mol] - 2 × [90.4 kJ/mol]δH° = - 277.5 kJ/mol

To know more about enthalpy change visit:-

https://brainly.com/question/28039996

#SPJ11

Choose the compound below that should have the highest melting point according to the ionic bonding model.
A) AlN
B) MgO
C) NaCl
D) CaS
E) RbI

Answers

According to the ionic bonding model, the compound with the highest melting point is likely to be the one with the strongest ionic bonds.

In the ionic bonding model, compounds form when there is a transfer of electrons from one element to another, resulting in the formation of positive and negative ions. The strength of the ionic bond is influenced by factors such as the charges and sizes of the ions involved.

Among the given compounds, MgO (magnesium oxide) is expected to have the highest melting point. This is because magnesium (Mg) is a metal that tends to lose two electrons and form a 2+ cation, while oxygen (O) is a nonmetal that tends to gain two electrons and form a 2- anion. The resulting Mg2+ and O2- ions have strong electrostatic attraction due to the opposite charges. This strong ionic bond requires a significant amount of energy to break, leading to a high melting point for MgO.

On the other hand, compounds like AlN (aluminum nitride), NaCl (sodium chloride), CaS (calcium sulfide), and RbI (rubidium iodide) also exhibit ionic bonding but with different ion sizes and charges. While these compounds have varying degrees of ionic bonding strength, they are expected to have lower melting points compared to MgO.

In conclusion, based on the ionic bonding model, MgO (option B) is likely to have the highest melting point among the given compounds due to its strong ionic bond resulting from the combination of a 2+ metal cation and a 2- nonmetal anion.

To learn more about compound -brainly.com/question/14186298

#SPJ11

Match the following.
Drag the terms on the left to the appropriate blanks on the right. Note: not all labels will be used.
ΔG>0, ΔG<ΔG∘, equilibrium, K=0, ΔG>ΔG∘, standard state, ΔG<0
1. Q > K -
2. Q > 1 -
3. Q = 1 -
4. Q < K -
5. Q = K -
6. Q < 1 -

Answers

a. ΔG>0 - 4. Q < K - This match indicates that if the change in Gibbs free energy (ΔG) for a reaction is greater than zero, it implies that the reaction is not at equilibrium.

a. ΔG>0 - 4. Q < K

b. ΔG<ΔG∘ - 1. Q > K

c. equilibrium - 5. Q = K

d. K=0 - Not applicable

e. ΔG>ΔG∘ - 2. Q > 1

f. standard state - Not applicable

g. ΔG<0 - 6. Q < 1

a. ΔG>0 - 4. Q < K

This match indicates that if the change in Gibbs free energy (ΔG) for a reaction is greater than zero, it implies that the reaction is not at equilibrium. In terms of the reaction quotient (Q) and the equilibrium constant (K), if Q is less than K, it means the reaction is not yet at equilibrium. This is because the ratio of the concentrations of the reactants and products, as represented by Q, is smaller than the equilibrium constant K, indicating that the reaction has not reached a state of equilibrium.

b. ΔG<ΔG∘ - 1. Q > K

When the change in Gibbs free energy (ΔG) for a reaction is less than the standard Gibbs free energy change (ΔG∘), it implies that the reaction is spontaneous in the forward direction. In terms of Q and K, if Q is greater than K, it means that the reaction has proceeded further than the equilibrium position, indicating that the reaction is spontaneous in the forward direction.

c. equilibrium - 5. Q = K

At equilibrium, the reaction quotient (Q) is equal to the equilibrium constant (K). This means that the concentrations of the reactants and products in the reaction have reached a balance, and there is no net change in the system over time.

d. K=0 - Not applicable

This label does not have a corresponding match. K=0 would indicate that the equilibrium constant is zero, which is not a valid scenario as equilibrium constants are always positive values.

e. ΔG>ΔG∘ - 2. Q > 1

When the change in Gibbs free energy (ΔG) for a reaction is greater than the standard Gibbs free energy change (ΔG∘), it indicates that the reaction is non-spontaneous in the forward direction. In terms of Q and K, if Q is greater than 1, it means that the reaction has proceeded further in the forward direction than it would be at equilibrium, indicating that the reaction is non-spontaneous in the forward direction.

f. standard state - Not applicable

This label does not have a corresponding match in the given options.

g. ΔG<0 - 6. Q < 1

If the change in Gibbs free energy (ΔG) for a reaction is less than zero, it implies that the reaction is spontaneous in the forward direction. In terms of Q and K, if Q is less than 1, it means that the reaction has not proceeded as far as it would be at equilibrium, indicating that the reaction is spontaneous in the forward direction.

The correct question is:

Match the following (a-g with 1.-6).  Note: not all labels will be used.

a. ΔG>0,

b. ΔG<ΔG∘

c. equilibrium

d. K=0

e. ΔG>ΔG∘

f. standard state

g. ΔG<0

1. Q > K

2. Q > 1

3. Q = 1

4. Q < K

5. Q = K

6. Q < 1

To know more about Gibbs free energy (ΔG) follow the link:

https://brainly.com/question/30870882

#SPJ4

1. what type of polymer would you obtain if sorbital (a sugar alcohol found in sugar free gum) was used as a plasticizer addictive?

2a. Starch-borate and starch-glycerol polymers have been used for encapsulation of pharmaceutical drugs or pesticides. Explain what effect ths might have and why it would be beneficial.

2b. Are these polymers considered to be biodegradable? why or why not?

Answers

1. The type of polymer that would you obtain if sorbitol is a polyol.

2a. The use of starch-borate and starch-glycerol polymers for the encapsulation of pharmaceutical drugs or pesticides would have a number of beneficial effects.

2b. Yes, these polymers are considered to be biodegradable.

1. The type of polymer that would you obtain if sorbitol (a sugar alcohol found in sugar-free gum) was used as a plasticizer additive is a polyol. This is because sorbitol is a polyol, which is a substance used to modify the properties of polymers. The process of polymer modification involves adding polyols to the polymer matrix, which helps to reduce the glass transition temperature of the polymer. Sorbitol can be used as a plasticizer addictive because it is a natural and non-toxic compound that is biodegradable.

2a. The use of starch-borate and starch-glycerol polymers for the encapsulation of pharmaceutical drugs or pesticides would have a number of beneficial effects. These polymers are natural and non-toxic, and they are biodegradable, which means that they do not pose a risk to the environment. Additionally, they can be used to modify the properties of the drugs or pesticides, making them more effective and reducing their toxicity.

2b. Yes, these polymers are considered to be biodegradable. This is because they are made from natural materials that can be broken down by biological processes. Starch-borate and starch-glycerol polymers are particularly attractive for use in biodegradable materials because they are non-toxic and biocompatible. They can be used in a variety of applications, including packaging materials, agricultural films, and medical devices, where their biodegradability is an important factor.

To know more about polyol visit:

https://brainly.com/question/32067095

#SPJ11

3. Define the following:
a. electromagnetic radiation
b. wavelength
c. frequency
d. quantum
e. photon

Answers

The answer will be a

Calculate the number of grams of Al3+ ions needed to replace 10 cmolc of Ca2+ ion from the exchange complex of 1 kg of soil
A soil has been determined to contain the exchangeable cations in these amounts: Ca2+ = 9 cmolc, Mg2+ = 3 cmolc, K+ = 1 cmolc, Al3+ = 3 cmolc. (a) What is the CEC of this soil? (b) What is the aluminum saturation of this soil?

Answers

a) The Cation Exchange Capacity, CEC, of the soil is 16 cmolc.

b) The aluminum saturation of the soil is approximately 18.75%.

What is the cation exchange capacity of the soil?

(a) The CEC (Cation Exchange Capacity) of the soil is calculated from the sum of the exchangeable cations present in the soil.

CEC = Ca²⁺ + Mg²⁺ + K⁺ + Al³⁺

CEC = 9 cmolc + 3 cmolc + 1 cmolc + 3 cmolc

CEC = 16 cmolc

(b) To calculate the aluminum saturation of the soil, we need to determine the percentage of the CEC occupied by Al³⁺ ions.

Aluminum Saturation = (Al³⁺ / CEC) * 100

Aluminum Saturation = (3 cmolc / 16 cmolc) * 100

Aluminum Saturation ≈ 18.75%

Learn more about cation exchange capacity at: https://brainly.com/question/30689981

#SPJ4

how many moles of o2- ions are there in 0.750 moles of aluminum oxide, al2o3?

Answers

In 0.750 moles of aluminum oxide (Al2O3), there are 2.25 moles of O2- ions. This is determined by the balanced chemical equation for the formation of aluminum oxide, which states that for every 1 mole of Al2O3, there are 3 moles of O2- ions.

By using a simple mole-to-mole conversion, we can calculate the number of moles of O2- ions present. Thus, with 0.750 moles of Al2O3, multiplying by the ratio of 3 moles O2- ions to 1 mole Al2O3 yields 2.25 moles of O2- ions. To determine the number of moles of O2- ions in 0.750 moles of aluminum oxide (Al2O3), we need to consider the balanced chemical equation for the formation of aluminum oxide. The formula for aluminum oxide indicates that for every 1 mole of Al2O3, there are 3 moles of O2- ions. Therefore, if we have 0.750 moles of Al2O3, we can calculate the number of moles of O2- ions as follows:

0.750 moles Al2O3 × (3 moles O2- ions / 1 mole Al2O3) = 2.25 moles O2- ions

Therefore, there are 2.25 moles of O2- ions in 0.750 moles of aluminum oxide, Al2O3.

Learn more about moles here : brainly.com/question/30885025
#SPJ11

With the aid of a periodic table, arrange the following in order of increasing electronegativity: Li, Na Ca
B, Be, Li
S, Se, Cl

Answers

The complete order of increasing electronegativity is:Be < B < Li < Na < Ca < S < Se < Cl

Electronegativity is the tendency of an atom to attract the electrons of a covalent bond towards itself. It can be arranged using a periodic table by determining the groups and periods. The trend is the increase of electronegativity from left to right and bottom to top. The elements that are further from each other in the periodic table will have a higher electronegativity.Here's how to arrange the following elements in order of increasing electronegativity:Li < Na < CaFor B, Be, Li, it is arranged as: Be < B < LiFor S, Se, Cl, it is arranged as: S < Se < ClSo, the complete order of increasing electronegativity is:Be < B < Li < Na < Ca < S < Se < Cl.

Learn more about electronegativity here:

https://brainly.com/question/3393418

#SPJ11

Compound A gives the product(s) below on oxidative cleavage with KMnO4 in acidic solution.
Propose a structure for A.
Compound A
(CH3)2C=O +
CH3CH2CH2CO₂H
You do not have to consider stereochemistry.
You do not have to explicitly draw H atoms.
If a group is achiral, do not use wedged or hashed bonds on it.

Answers

Compound A is likely a compound containing a central carbon atom bonded to two methyl groups, followed by a carbon chain of three carbons ending with a carbonyl group.

Based on the given reaction of oxidative cleavage with KMnO₄ in an acidic solution, the products formed are:

Compound A → (CH₃)₂C=O + CH₃CH₂CH₂CO₂H

From this, we can deduce that Compound A must be a compound that, upon oxidative cleavage, yields acetone [(CH₃)₂C=O] and a carboxylic acid (CH₃CH₂CH₂CO₂H).

To propose a structure for Compound A, we need to consider the functional groups and the products formed.

1. Acetone (CH₃)₂C=O: This is a ketone functional group, consisting of a carbon double-bonded to an oxygen atom, with two methyl groups attached to the same carbon atom.

2. Carboxylic acid (CH₃CH₂CH₂CO₂H): This is a carboxylic acid functional group, consisting of a carbon double-bonded to an oxygen atom (carbonyl group) and a hydroxyl group (-OH) attached to the same carbon atom. The carbon atom is further bonded to an ethyl group (CH₂CH₂) and a hydrogen atom (H).

Based on these products, a possible structure for Compound A is:

In this structure, the central carbon atom is bonded to two methyl groups (CH₃) and is connected to an ethyl group (CH₂CH₂) and a carboxylic acid group (COOH).

Learn more about oxidative cleavage here:

https://brainly.com/question/32677709

#SPJ4

calculate+the+empirical+formula+from+the+given+percent+compositions.+82%+nitrogen+(n),+18%+hydrogen+(h)

Answers

The mole ratio for 82% nitrogen (N) and 18% hydrogen (H) is roughly 1:3. As a result, the compound's empirical formula is NH₃ (one nitrogen and three hydrogen atoms).

To calculate the empirical formula from the given percent compositions, we need to convert the percentages into moles and find the simplest whole-number ratio between the elements. Here's the calculation:

Assuming we have 100 grams of the compound, we would have:

- 82 grams of nitrogen (N)

- 18 grams of hydrogen (H)

Now, we need to convert these masses into moles using the molar mass of each element:

- Nitrogen (N): 1 mole of N = 14.01 grams

[tex]\begin{equation}\text{Moles of N} = \frac{82 \text{ grams}}{14.01 \text{ g/mol}} \approx 5.85 \text{ mol}[/tex]

- Hydrogen (H): 1 mole of H = 1.01 grams

[tex]\[\text{Moles of H} = \frac{18 \text{ g}}{1.01 \text{ g/mol}} \approx 17.82 \text{ mol}\][/tex]

Next, we need to find the simplest whole-number ratio between nitrogen and hydrogen by dividing each number of moles by the smaller value (5.85 mol, in this case):

[tex]\[\text{Moles of N (rounded)} = \frac{5.85 \text{ mol}}{5.85 \text{ mol}} = 1\][/tex]

[tex]\[\text{Moles of H (rounded)} = \frac{17.82 \text{ mol}}{5.85 \text{ mol}} \approx 3.04\][/tex]

The ratio between N and H is approximately 1:3, so the empirical formula of the compound is NH₃ (1 nitrogen atom, 3 hydrogen atoms).

To know more about the mole ratio refer here :

https://brainly.com/question/32125056#

#SPJ11

This figure illustrates which of the following? gamma emission
fusion
chain reaction
beta emission

Answers

Answer:chain reaction

Explanation:

STRONG acids and bases. (Assume pOH + pH = 14).
calculate the concentration of (OH-) for a 0.0545 M solution of hydrochloric acid (HCI)

Answers

The concentration of OH- for a 0.0545 M solution of hydrochloric acid (HCl) is 7.21 x 10^-13 M.

Let's first understand the concepts of acids and bases and strong acids and bases.

Acids are proton donors, and bases are proton acceptors. The strength of an acid or a base is determined by the extent to which it donates or accepts protons. Strong acids and bases dissociate completely in water, while weak acids and bases dissociate only partially.

Thus, a strong acid or base has a high concentration of H+ or OH-, respectively.
Now let's solve the problem. We are given a 0.0545 M solution of hydrochloric acid (HCl).

Since HCl is a strong acid, it dissociates completely in water according to the equation:

HCl → H+ + Cl-

The concentration of H+ in the solution will be equal to the concentration of HCl, which is 0.0545 M.
Since we know that

pOH + pH = 14,

we can calculate the pOH of the solution using the pH:

pH = -log[H+]

pH = -log(0.0545)

pH = 1.2648
Now,

pOH + pH = 14

can be rewritten as:

pOH = 14 - pH

pOH = 14 - 1.2648

pOH = 12.7352
The concentration of OH- can be calculated using the pOH:

pOH = -log[OH-]

12.7352 = -log[OH-]

[OH-] = 7.21 x 10^-13
Therefore, the concentration of OH- for a 0.0545 M solution of hydrochloric acid (HCl) is 7.21 x 10^-13 M.

To know more about hydrochloric acid visit:

https://brainly.com/question/24784580

#SPJ11

50 ml of 0.600 m sr(no3)2 with 50 ml of 1.60 m kio3 caculatte the equilibreum sr2

Answers

The equilibrium Sr2+ is 0.15 M.

The chemical reaction that occurs when 50 ml of 0.600 M Sr(NO3)2 reacts with 50 ml of 1.60 M KIO3 is: 2 Sr(NO3)2 + 2 KIO3 → Sr(IO3)2 + 2 KNO3From this balanced equation, it can be seen that 2 moles of Sr(NO3)2 produce 1 mole of Sr(IO3)2.

Therefore, moles of Sr(NO3)2 present initially = 0.600 × 0.050 = 0.03 mol Moles of KIO3 present initially = 1.60 × 0.050 = 0.08 mol

Since the ratio of moles of Sr(IO3)2 to Sr(NO3)2 is 1:2, therefore moles of Sr(IO3)2 formed = 0.03 / 2 = 0.015 mol

The final volume of the mixture is 50 + 50 = 100 ml

Number of moles of Sr(IO3)2 in 100 ml solution = 0.015 mol

Molarity of Sr(IO3)2 = (Number of moles of Sr(IO3)2) / (Volume of solution in L) = (0.015 mol) / (0.100 L) = 0.15 M

Therefore, the equilibrium Sr2+ is 0.15 M.

Know more about equilibrium :

https://brainly.com/question/30325987

#SPJ11

The equilibrium Sr²⁺ concentration in the solution will be approximately 0.600 mol/L.

To calculate the equilibrium Sr²⁺ concentration in the solution, we need to determine whether a precipitation reaction occurs between Sr(NO₃)₂ and KIO₃, and if so, how much Sr²⁺ precipitates.

The balanced chemical equation for the precipitation reaction between Sr(NO₃)₂ and KIO₃ is;

2Sr(NO₃)₂ + KIO₃ → Sr(IO₃)₂ + 2KNO₃

We can see that for every 2 moles of Sr(NO₃)₂, 1 mole of Sr(IO₃)₂ precipitates.

First, let's calculate the moles of Sr(NO₃)₂ and KIO3 in the solution;

Moles of Sr(NO₃)₂ = Volume (L) × Concentration (M)

= 0.050 L × 0.600 M

= 0.030 mol

Moles of KIO₃ = Volume (L) × Concentration (M)

= 0.050 L × 1.60 M

= 0.080 mol

From the balanced equation, we can see that the limiting reagent is Sr(NO₃)₂ because it has fewer moles than KIO₃.

Since 2 moles of Sr(IO₃)₂ precipitate for every 2 moles of Sr(NO₃)₂, we can conclude that all the Sr(NO₃)₂ will react and form Sr(IO₃)₂.

Now, let's calculate the concentration of Sr²⁺ ions in the solution after the reaction:

The total volume of the solution is 50.0 mL + 50.0 mL = 0.100 L

Since 2 moles of Sr(NO₃)₂ give 2 moles of Sr²⁺ ions, and we have 0.030 mol ofSr(NO₃)₂;

Concentration of Sr²⁺ ions = Moles of Sr²⁺ ions/Volume of the solution

= (2 × 0.030 mol) / 0.100 L

= 0.600 M

Therefore, the equilibrium Sr²⁺ concentration in the solution is 0.600 mol/L.

To know more about precipitation reaction here

https://brainly.com/question/29762381

#SPJ4

--The given question is incomplete, the complete question is

"A solution is prepared by mixing 50.0 mL of 0.600 M Sr(NO₃)₂ with 50.0 mL of 1.60 M KIO₃. Calculate the equilibrium Sr²⁺ concentration in mol/L for this solution. Ksp for Sr(IO₃)₂ = 2.30E-13."--

la) Determine the upper and lower bounds for an Al2O3 particle - Al matrix composite E(Al)-69 GPa, E(AlbO3)-380 GPa, Volume fraction(Al)-0.40 (1b) Calculate the upper bound for the specific stiffness of this composite. p(Al)-2.71 g/cm3, pAbO3 3.98 g/cm3

Answers

The upper bound for the specific stiffness of this composite is 25.36 x 10^6 N/m3.

Upper and lower bounds for an Al2O3 particle - Al matrix composite E(Al)-69 GPa, E(AlbO3)-380 GPa, Volume fraction(Al)-0.40The rule of mixtures is a tool that is used to estimate the properties of composites. This rule is based on the following equation:Em=E1V1+E2V2Where, E is the modulus of elasticity, V is the volume fraction, and the subscripts 1 and 2 denote the individual phases. For this case, we have two phases: Al and Al2O3 particles.To find the upper and lower bounds, we'll use the following equation:Em=V1E1+V2E2Lower bound:Em = 0.4(69) + 0.6(380) = 243 GPaUpper bound:Em = 0.6(69) + 0.4(380) = 177 GPab) Calculate the upper bound for the specific stiffness of this composite.p(Al)-2.71 g/cm3, pAl2O3 3.98 g/cm3Specific stiffness is defined as the ratio of the elastic modulus to density.Specific stiffness, E/ρ = Em/Vm, where Vm is the total volume and can be calculated as:Vm = V1 + V2 = 0.4 + 0.6 = 1.E/ρ= Em/VmSo the upper bound is:E/ρ=177/((0.4 x 2.71) + (0.6 x 3.98))=25.36 x 10^6 N/m3Ans: The upper bound for the specific stiffness of this composite is 25.36 x 10^6 N/m3.

Learn more about stiffness here:

https://brainly.com/question/31172851

#SPJ11

Calculate the change in pH when 9.00 mL of 0.100 M HCl(aq) is added to 100.0 mL of a buffer solution that is 0.100 M in NH3(aq) and 0.100 M in NH4Cl(aq). Consult the table of ionization constants as needed.
ΔpH=
Calculate the change in pH when 9.00 mL of 0.100 M NaOH is added to the original buffer solution.
ΔpH=

Answers

In both cases, the change in pH is 0.18 because the amount of HCl or NaOH added is equal to the buffer capacity of the buffer solution.

How to find pH?

The buffer solution is a weak base-weak acid buffer. The pH of a buffer solution is given by the Henderson-Hasselbalch equation:

pH = pKa + log([A⁻]/[HA])

where:

pH = pH of the solution

pKa = negative logarithm of the acid dissociation constant

[A⁻] = concentration of the conjugate base

[HA] = concentration of the acid

The pKa of ammonia is 9.25. The concentration of ammonia is 0.100 M and the concentration of ammonium chloride is 0.100 M.

Substituting these values into the Henderson-Hasselbalch equation:

pH = 9.25 + log([NH₃]/[NH₄Cl])

pH = 9.25 + log(0.100/0.100)

pH = 9.25

When 9.00 mL of 0.100 M HCl is added to the buffer solution, the concentration of HCl is 0.0090 M. The HCl will react with the ammonia in the buffer solution to form ammonium chloride. The reaction is:

HCl + NH₃ ⇔ NH₄Cl

The concentration of ammonia will decrease and the concentration of ammonium chloride will increase. The new concentration of ammonia will be 0.091 M and the new concentration of ammonium chloride will be 0.109 M.

Substituting these values into the Henderson-Hasselbalch equation:

pH = 9.25 + log(0.091/0.109)

pH = 9.07

The change in pH is:

ΔpH = 9.25 - 9.07 = 0.18

Calculating the change in pH when 9.00 mL of 0.100 M NaOH is added to the original buffer solution:

The NaOH will react with the ammonium chloride in the buffer solution to form ammonia and water. The reaction is:

NaOH + NH₄Cl ⇔ NH₃ + H₂O + NaCl

The concentration of ammonia will increase and the concentration of ammonium chloride will decrease. The new concentration of ammonia will be 0.109 M and the new concentration of ammonium chloride will be 0.091 M.

Substituting these values into the Henderson-Hasselbalch equation:

pH = 9.25 + log(0.109/0.091)

pH = 9.43

The change in pH is:

ΔpH = 9.43 - 9.25 = 0.18

In both cases, the change in pH is 0.18. This is because the amount of HCl or NaOH added is equal to the buffer capacity of the buffer solution. The buffer capacity is the amount of acid or base that can be added to a buffer solution before the pH changes by 1 unit.

Find out more on pH here: https://brainly.com/question/26424076

#SPJ4

Plutonium is a radioactive material, exposure to which is hazardous to human health, and is one of the few materials that can be used to make a nuclear weapon. The time it takes for half of any initial quantity of plutonium to decay into stable non-radioactive products is roughly:

Answers

Answer:

24,000 years

Explanation:

Define diffusion use the words concentration gradient in a sentence.

Answers

Diffusion is the process by which particles (such as molecules, ions, or atoms) move from an area of higher concentration to an area of lower concentration, driven by the concentration gradient.

A concentration gradient refers to the difference in concentration between two regions. In diffusion, particles move randomly and collide with each other, causing them to spread out and distribute themselves evenly.

As particles move from higher concentration to lower concentration, the concentration gradient decreases, resulting in the equalization of concentrations over time. This movement occurs due to the natural tendency of particles to achieve a state of equilibrium, where there is no net movement of particles across the concentration gradient.

Diffusion plays a crucial role in various biological, physical, and chemical processes, such as gas exchange in the lungs, the transport of nutrients across cell membranes, and the mixing of substances in solutions.

To know more about the concentration gradient refer here :

https://brainly.com/question/13680237#

#SPJ11

Without doing any calculations, determine the sign of ΔSsys for each of the following chemical reactions. which is ΔSsys greater than 0 and which is ΔSsys smaller than 0.
a) 2H3O^+ (aq) + CO3^2- (aq) --> CO2 (g) + 3H2O (l)
b) CH4 (g) + 2O2 (g) --> CO2 (g) + 2H2O (l)
c) PCl3 (l) + Cl2 (g) --> PCl5 (s)
d) SO3 (g) + H2O (l) --> H2SO4 (l)

Answers

Change in entropy of the system ΔSsys would be positive, negative, negative, negative respectively.

The term "ΔSsys" refers to the change in entropy of the system. The entropy change of a system is determined by considering the system's state before and after the reaction occurred. Here are the sign of ΔSsys for each of the given chemical reactions:

a) 2H3O+ (aq) + CO32- (aq) → CO2 (g) + 3H2O (l)

The reaction involves the formation of one gas molecule and three liquid molecules from two aqueous solutions. Because gas molecules have a higher entropy than liquids, the entropy of the system would rise if the reaction were to take place. Therefore, ΔSsys would be positive.

b) CH4 (g) + 2O2 (g) → CO2 (g) + 2H2O (l)

The reaction involves the formation of one gas molecule and two liquid molecules from two gas molecules. The entropy of the system would therefore decrease. Therefore, ΔSsys would be negative.

c) PCl3 (l) + Cl2 (g) → PCl5 (s)The reaction involves the formation of a solid product from a liquid and a gas. Because solids have lower entropy than liquids or gases, the entropy of the system would decrease. Therefore, ΔSsys would be negative.

d) SO3 (g) + H2O (l) → H2SO4 (l)The reaction involves the formation of a liquid from two gases. The entropy of the system would therefore decrease. Therefore, ΔSsys would be negative.

Learn more about Change in entropy here:

https://brainly.com/question/28244712

#SPJ11

Which of the following is not a colorimetric method for Protein Quantitation? a. Biuret Test b. Folin-Ciocalteu (Lowry) Assay c. Bradford Assay d. Amino Acid Analysis e. Bicinchoninic Acid (BCA) Assay

Answers

The correct option is (d.) Amino Acid Analysis. While a valuable technique for amino acid composition analysis, is not a colorimetric method for protein quantitation.

Amino Acid Analysis is not a colorimetric method for protein quantitation. It is a technique used to determine the composition and concentration of amino acids in a protein sample, but it does not rely on colorimetric reactions to quantify the protein content.

The other options listed (a. Biuret Test, b. Folin-Ciocalteu (Lowry) Assay, c. Bradford Assay, and e. Bicinchoninic Acid (BCA) Assay) are all colorimetric methods commonly used for protein quantitation.

Amino Acid Analysis, while a valuable technique for amino acid composition analysis, is not a colorimetric method for protein quantitation. The other methods mentioned are commonly used for protein quantitation and rely on colorimetric reactions to measure protein concentration.

To know more about colorimetric , visit:

https://brainly.com/question/30227806

#SPJ11

C2H5OH(l)+3O2(g)→2CO2(g)+3H2O(g)
If 9.2g of C2H5OH(l) burns completely in the presence of excess O2(g) according to the equation, how many grams of CO2(g) are produced?
A:0.40g
B:8.8g
C:9.2g
D:18g

Answers

Answer:

D. 18g

Explanation:

To get the answer, we will use an equation to convert the grams of C2H5OH to moles of C2H5OH, then I will convert the moles of C2H5OH to moles of CO2, and then I will convert the moles of CO2 to grams of CO2.

9.2g C2H5OH / 46.07g C2H5OH = 0.199 mol C2H5OH

0.199 mol C2H5OH (2 mol CO2 / 1 mol C2H5OH) = 0.398 mol CO2

0.398 mol CO2 (44.01g CO2 / 1 mol CO2) = 17.515g CO2

The answer closest to our answer is answer choice D. 18g

Therefore, the answer is D

In normal temperatures, carbon dioxide is a colorless, non-flammable gas, its calculated value is "18 gram".

Carbon dioxide calculation:

Equation:

[tex]\to \bold{C_2H_5OH\ (l)+3O_2\ (g) \to 2CO_2\ (g)+3H_2O\ (g)}[/tex]

In the above-given scenario, We'll utilize an equation that converts grams of ethanol to moles of ethanol, then converts moles of ethanol to moles of carbon dioxide, and finally, transforms the moles of carbon dioxide into grams of carbon dioxide to get the result.

Following are the calculation of the conversion of carbon dioxide:

[tex]\to \frac{9.2\ g\ C_2H_5OH }{46.07\ g\ C_2H_5OH} = 0.199\ mol C_2H_5OH\\\\\to 0.199\ mol\ C_2H_5OH \ (\frac{2\ mol\ CO_2}{ 1\ mol\ C_2H_5OH}) = 0.398\ mol\ CO_2\\\\\to 0.398\ mol \ CO_2 \ (\frac{44.01\ g\ CO_2}{1 \ mol\ CO_2}) = 17.515\ g\ CO_2 \approx 18\ g \ CO_2\\\\[/tex]

Therefore, the answer is "Option D".

Find out more about the CO2 here:

brainly.com/question/867804

Select which of the following is a major disadvantage of using nuclear power to generate electricity.



The power plants are inexpensive to build


A small amount of power is produced


No greenhouse gases are produced


The by-product of nuclear power is radiation

Answers

Answer:

The power plants

are inexpensive to build

Based on the reduction potential data, What is the standard cell potential for the following electrochemical cell reaction: Zn(s) + Cu^2+(aq) Zn^2+(aq) + Cu(s)? E degree red = -0.763 V for Zn^2+ (aq) + 2e^- Zn(s) E degree red = +0.340 V for Cu^2+(aq) + 2e^- Cu(s). a. -0.423 V b. +1.10 V c. +0.423 V

Answers

Based on the reduction potential data, the standard cell potential for the electrochemical cell reaction is +1.10 V. The correct answer is B.

The standard cell potential is the difference between the standard reduction potentials of the two half-reactions. In this case, the half-reactions are:

Zn(s) + 2e- -> Zn²⁺(aq) E° red = -0.763 V

Cu²⁺(aq) + 2e- -> Cu(s) E° red = +0.340 V

The standard cell potential is therefore:

E° cell = E° red (cathode) - E° red (anode)

E° cell = +0.340 V - (-0.763 V)

E° cell = +1.10 V

Therefore, the correct option is B, +1.10 V.

To know more about standard cell potential, refer here:

https://brainly.com/question/29797132#

#SPJ11

During the microscopic observation of a drop of stagnant pond water, what criteria would you use to distinguish viable organisms from nonviable suspended debris? 50 Experiment 6: Lab Report 5. Because of a snowstorm, your regular laboratory session was can- celed and the Gram staining procedure was performed on cultures incubated for a longer period of time. Examination of the stained B. cereus slides revealed a great deal of color variability, ranging from an intense blue to shades of pink Account for this result. 5. Upon observation of the nutrient agar slant culture, you strongly sus- pect that the culture is contaminated. Outline the method you would follow to ascertain whether your suspicion is justified. 18 Experiment 2: Lab Report

Answers

1. Criteria used to distinguish viable organisms from nonviable suspended debris are motility, shape and structure.

2. The variability in color observed during Gram staining of B. cereus slides, ranging from intense blue to shades of pink, can be attributed to the extended incubation period.

3. We can use Visual Examination and Smell Test to ascertain whether your suspicion is justified.

1. To distinguish viable organisms from nonviable suspended debris in a drop of stagnant pond water during microscopic observation, the following criteria can be used:

Motility: Observe if the organisms are showing any signs of movement. Viable organisms are more likely to exhibit motility, while nonviable debris will remain stationary.Shape and Structure: Examine the morphology and structure of the organisms. Viable organisms will typically have distinct shapes and structures, such as identifiable cell walls, organelles, or appendages. Nonviable debris may appear more amorphous and lack identifiable cellular structures.Reproduction: Look for signs of reproductive structures, such as budding, spores, or division. Viable organisms will display reproductive capabilities, while nonviable debris will not exhibit such characteristics.Cellular Integrity: Assess the overall integrity of the cells. Viable organisms will have intact and well-defined cellular structures, while nonviable debris may show signs of degradation or disintegration.By considering these criteria, you can differentiate between viable organisms and nonviable suspended debris in the pond water sample.

2. The variability in color observed during Gram staining of B. cereus slides, ranging from intense blue to shades of pink, can be attributed to the extended incubation period. Gram staining is a differential staining technique used to categorize bacteria into two major groups: Gram-positive and Gram-negative, based on their cell wall composition.

During prolonged incubation, B. cereus cells may undergo physiological changes, including alterations in their cell wall structure and composition. These changes can affect the uptake and retention of the Gram stain.Intense blue coloration indicates that the cells retained the crystal violet dye, characteristic of Gram-positive bacteria. Shades of pink, on the other hand, suggest that the cells did not retain the crystal violet dye effectively, potentially due to modifications in their cell wall or the presence of Gram-negative-like characteristics.Extended incubation can lead to variations in the Gram staining results, highlighting the importance of performing the staining procedure within the recommended timeframe to obtain accurate and consistent results.

3. To ascertain whether a nutrient agar slant culture is contaminated, the following steps can be followed:

Visual Examination: Observe the nutrient agar slant culture for any visible signs of contamination, such as discoloration, abnormal growth, or presence of mold, fungal growth, or unusual colonies. Any visible signs of contamination indicate a potential problem.Smell Test: Take a whiff of the culture to detect any unusual or foul odors. Strong, unpleasant odors may indicate contamination.Subculturing: Take a small portion of the suspected contaminated culture and streak it onto a fresh nutrient agar plate. Incubate the plate under appropriate conditions. If the suspected contaminants grow as separate colonies on the fresh plate, it confirms the presence of contamination.Microscopic Examination: Prepare a microscope slide by placing a small amount of the suspected contaminated culture onto a slide and observe under a microscope. Look for any unusual or non-characteristic microbial morphology that could indicate contamination.Confirmatory Tests: Perform additional specific tests or assays, if available, to confirm the nature of the contamination. For example, biochemical tests, molecular techniques, or selective media can be used to identify the contaminants and differentiate them from the desired culture.

By following these steps, you can gather evidence to determine whether a nutrient agar slant culture is contaminated or not.

The correct question is:

1. During the microscopic observation of a drop of stagnant pond water, what criteria would you use to distinguish viable organisms from nonviable suspended debris?

2. Because of a snowstorm, your regular laboratory session was canceled and the Gram staining procedure was performed on cultures incubated for a longer period of time. Examination of the stained B. cereus slides revealed a great deal of color variability, ranging from an intense blue to shades of pink Account for this result.

3. Upon observation of the nutrient agar slant culture, you strongly suspect that the culture is contaminated. Outline the method you would follow to ascertain whether your suspicion is justified.

To know more about Gram staining follow the link:

https://brainly.com/question/4129405

#SPJ4

Other Questions
Carns Company is considering eliminating its Small Tools Division, which reported a loss for the prior year of $205,000 as shown below. Segment Income (Loss) Sales $ 1,430,000 Variable costs 1,295,000 Contribution margin 135,000 Fixed costs 340,000 Income (loss) $ (205,000) If the Small Tools Division is dropped, all of its variable costs are avoidable, and $119,000 of its fixed costs are avoidable. The impact on Carnss income from eliminating the Small Tools Division would be: Multiple Choice construct a rhombus with a 15 degree angle and sides equal to r. Write down an expression for the perimeter of a rectangle. With length-L and width-W given your answer. PLS HELPI WILL MARK BRAINLIESTIF YOU DONT KNOW DONT ANSWERSOLVE FOR X IN THE 4 PROBLEMS Why is a dictatorship a cause of war?Ready? Enter your ans What makes the Caribbean Islands?A. Mountains on landB. PeninsulasC. Tops of submerged mountainsD. Plateaus what is the equation of the quadratic graph witha focus of (3,4) and a directrtix of y=8 A.) 660B.) 418.93C.) 320.1 An overdetermined linear system Ax = b must be inconsistent for some vector b. Find all values of b_1,b_2, b_3, b_4, and b_5 for which the following overdetermined linear system is inconsistent: x_1 - 3x_2=b_1 x_1 - 2x_2 = b_2 x_1 + x_2 = b_3 x_1 - 4x_2 = b_4 x_1 + 5x_2 = b_5 nad is directly involved a) only glycolysis b) only ppp c) both pathways d) neither pathway Which of the following is the correct binomial format? O Genus species O Phylum class O Species O Order family A guitar string 61 cm long vibrates with a standing wave that has three antinodes.1-Which harmonic is this? Express your answer using one significant figure.2-What is the wavelength of this wave? Express your answer using two significant figures. HELP ME PLS, the function- If the rate of change of the graph of a linear equation is 4 and the y-intercept is (0, 8), what is the linear equation that represents the graph? For the reaction2S(s)+ 3O2\rightarrow 2SO3(g)how many moles of SO3 can be produced from 6.0 g O2 and excess S?Group of answer choicesnone of these0.28 mol SO34.0 mol SO30.25 mol SO30.13 mol SO3 If you are considering moving to a matrixed organization, you will need: 1. both time and budget allocated. 2. strong leadership. 3. both time and strong leadership. 4. time. 5. budget allocated. Assume IQ scores are normally distributed with a mean of 100 and standard deviation 10. Determine the percent probability that a randomly chosen person as an IQ LESS THAN 90 please help I'm stuck7. Which of the following correctly defines an acid-base reaction?a. redox reactionb. neutralization reactionC. combustion reactiond. hydrolysis reaction Anatomy and Phys PLEASE HELP youve learned about the structures that make up the reproductive system. Imagine that you are so interested in reproductive health that you are exploring careers related to this health field.For this activity you are going to research careers related to the promotion or treatment of reproductive health and choose one career to focus on. You are going to identify the key factors of the educational path that you would need to take to work in this career, the annual salary that you would earn, the schedule that you may find yourself working, physical requirements for the job, and how long it will take you to achieve this goal.You will produce a list of 10 or more strengths and weaknesses that will identify why you are qualified for this role.You will then prepare a list of at least five questions that you would like to ask someone already working in the career. Your questions ought to be relevant to the career you have chosen and should be related to the research that you have conducted. How did the county of Boulder, Colorado, respond to the flood in 2013?Question 10 options:Repaired damaged roads and found other routesAsked citizens to fix the road themselvesLeft broken roads in disrepairDecided the county did not need the damaged roads